nav emailalert searchbtn searchbox tablepage yinyongbenwen piczone journalimg journalInfo journalinfonormal searchdiv searchzone qikanlogo popupnotification paper paperNew
2006, 03, 1-3+9
Progress on Synthesis and Application of Polycaprolactone
Email:
DOI:
Published:   2006-03-25
Publication Date:   2006-03-25
Mobile reading
Abstract:

The properties,synthesis and application of polycaprolactone are reviewed.Main initiation systems,auxiliary means for the ring-opening polymerization of ε-caprolactone to obtain polycaprolactone and their application as biomedical materials are focused on and the developing direction is respected.

References

[1]Rohner D,Hutmacher D W,See P,et al.Individually CAD-CAMtechnique designed,bioresorbable 3-dimensional polycaprolactoneframework for experimental reconstruction of craniofacial defectsin the pig[J].Mund Kiefer Gesichtschir,2002,6(3):162-167.

[2]Bixler K J,Calhoun G C,Scholsky K M,et al.Polymerization ofepsilon-caprolactone in the presence of carboxylic acids[J].Poly-mer Preprints,1990,31(2):494-495.

[3]张其锦,王冰,罗筱烈,等.双羧基封端聚己内酯的合成与表征[J].应用化学,1994,11(2):57-61.

[4]Gross R A,Kumar A,Kalra B.Polymer synthesis by in vitro en-zyme catalysis[J].Chem Rev,2001,101:2097-2124.

[5]Ajay Kumar,Bhanu Kalra,Alex Dekhterman,et al.Efficientring-opening polymerization and copolymerization ofε-caprolac-tone and-ωpentadecalactone catalyzed by candida antartica lipaseB[J].Macromolecules,2000,33(17):6303-6309.

[6]Foresti M L,Ferreira M L.Synthesis of polycaprolactone usingfree/supported enzymatic and non-enzymatic catalysts[J].Macro-mol Rapid Commun,2004,25:2025-2028.

[7]刘建飞,沈之荃,孙俊全.稀土乙酰丙酮盐催化聚合ε-己内酯和丙交酯[J].应用化学,1995,12(6):59-61.

[8]Xu Lina,Jiang Liming,Sun Weilin,et al.Novel Sm(PPh2)2initia-tor for the synthesis of poly(ε-caprolactone)with linear and star-shaped structures[J].Polymer Bulletin,2002,49:17-23.

[9]Lisa Saunders Baugh,Joseph A Sissano.Polymerization of methylmethacrylate and other polar monomers with alkylaluminum initi-ators bearing bidentate and tridentateN-andO-donor ligands[J].J Polym Sci Part A:Polym Chem,2002,40:1633-1651.

[10]Joseph Jagur-Grodzinski.Functional polymers by living anionicpolymerization[J].J Polym Sci Part A:Polym Chem,2002,40:2116-2133.

[11]Kim Moon Suk,Faust Rudolf.Synthesis of poly(ε-caprolactone--bisobutylene)diblock copolymer and poly(ε-caprolactone-b-iso-butylene-b-ε-caprolactone)triblock copolymer[J].Polymer Bul-letin,2002,48:127-134.

[12]刘立建,廖立琼,宋英,等.己内酯和丙交酯的微波辅助开环聚合反应[J].高分子通报,2003,(5):1-6.

[13]Fang Xiaomei,Ronald Hutcheon,Daniel A Scola.Microwavesyntheses of poly(ε-caprolactam-co-ε-caprolactone)[J].J PolymSci Part A:Polym Chem,2000,38(8):1379-1390.

[14]Degirmenci Mustafa,Hizal Gurkan,Yagci Yusuf.Synthesis andcharacterization of macrophotoinitiators of poly(ε-caprolactone)and their use in block copolymerization[J].Macromolecules,2002,35:8265-8270.

[15]Stassin Fabrice,Jerome Robert.Polymerization of(L,L)-lactideand copolymerization withε-caprolactone initiated by dibutyltindimethoxide in supercritical carbon dioxide[J].Journal of Poly-mer Science Part A:Polymer Chemistry,2005,43:2777-2789.

[16]Qian Haitao,Bei Jiangzhong,Wang Shenguo.Synthesis,charac-terization and degradation of ABA block copolymer of L-lactideandε-caprolactone[J].Polymer Degradation and Stability,2000,68:423-429.

[17]John J,Tang J,Bhattacharya M.Processing of biodegradableblends of wheat gluten and modified polycaprolactone[J].Poly-mer,1998,39(13):2883-2895.

[18]John J,Bhattacharya M.Properties of reactively blended soy proteinand modified polyesters[J].Polym Int,1999,48:1165-1171.

[19]宋存先,王彭延,孙洪范,等.聚己内酯在体内的降解、吸收和排泄[J].J Biomed Eng,2000,17(1):25-28.

[20]Goh J C H,Shao X X,Hutmacher D W,et al.Tissue engineeringapproach to osteochondral repair and regeneration[J].Journal ofMechanics in Medicine and Biology,2004,4(4):463-483.

[21]Groot JH DE,Penning A J,Coenen J.Triple-layer artificial skin:porous 50/50 copoly(L-lactide/ε-caprolactone)template for neo-dermis regeneration[J].J Mat Sci Lett,1997,16(2):153-154.

[22]杨立燕,柴淑玲,谭慧民.二醋酸纤维素接枝己内酯的核磁共振表征[J].功能高分子学报,2004,17(1):135-138.

Basic Information:

China Classification Code:O633.14

Citation Information:

[1]WANG Yong-liang,YI Guo-bin,KANG Zheng,XIONG Fu-hua,ZHOU Ping,CUI Yi-hua(Faculty of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510006,China).Progress on Synthesis and Application of Polycaprolactone[J].Chemistry & Bioengineering,2006(03):1-3+9.

Fund Information:

广州市科技计划项目(2001-Z-101-01); 广东省教育厅自然科学基金资助项目(Z02030)

Published:  

2006-03-25

Publication Date:  

2006-03-25

quote

GB/T 7714-2015
MLA
APA